Correlation of Vapor-Liquid Equilibrium Relationship in Binary Systeme

Liquid - Vapor Equilibrium/Distillation

Background The volatility of a compound is its ability to change into a vapor, or to evaporate at a particular temperature and pressure. The normal boiling point of a liquid usually allows comparison of its volatility to other materials, with lower boiling points indicating greater volatility, but this may be affected somewhat by the presence of other materials. Comparison of the concentration ...

Non-equilibrium structure of the vapor-liquid interface of a binary fluid

The evaporation of a binary liquid mixture of monatomic species into near vacuum has been investigated by molecular dynamics simulations. It has been assumed that atomic interaction forces can be derived by Lennard-Jones potentials. Results are presented about surface composition changes induced by evaporation, the shape of the distribution functions of evaporating atoms. Estimates of evaporati...

Isobaric Vapor-Liquid Equilibrium of Binary Mixture of Methyl Acetate with Isopropylbenzene at 97.3 kPa

Isobaric vapor-liquid equilibrium measurements are reported for the binary mixture of Methyl acetate and Isopropylbenzene at 97.3 kPa. The measurements have been performed using a vapor recirculating type (modified Othmer's) equilibrium still. The mixture shows positive deviation from ideality and does not form an azeotrope. The activity coefficients have been calculated taking into considerati...

Isobaric Vapor-Liquid Equilibrium Data for Binary Mixture of 2-Methyltetrahydrofuran and Cumene

Isobaric vapor-liquid equilibrium measurements are reported for binary mixture of 2-Methyltetrahydrofuran and Cumene at 97.3 kPa. The data were obtained using a vapor recirculating type (modified Othmer's) equilibrium still. The mixture shows slight negative deviation from ideality. The system does not form an azeotrope. The experimental data obtained in this study are thermodynamically consist...

Gibbs ensemble simulation of liquid-vapor equilibrium in quantum neon